oxidation - ANSWER-loss of electrons, positive charge atoms (anode)
reduction - ANSWER-gain of electrons, negative charged atoms (cathode)
forms of corrosion - ANSWER-uniform, crevice, galvanic (dissimilar metals)
...
oxidation - ANSWER-loss of electrons, positive charge atoms (anode)
reduction - ANSWER-gain of electrons, negative charged atoms (cathode)
forms of corrosion - ANSWER-uniform, crevice, galvanic (dissimilar metals) if two metals have to be couple then best to couple metals close together in the galvanic series, pitting, intergranular, selective leaching (dezincification, graphitization), velocity phenomena, environmental cracking (corrosion fatigue, hydrogen embrittlement, SCC (Carbonates/bicarbonates)
High PH - ANSWER-Low hydrogen, alkaline, easy polarization
Low PH - ANSWER-high hydrogen, acidic, harder to polarize
High oxygen/High Hydrogen concentration - ANSWER-harder to polarize, work at the cathode only, called cathodic depolarizers.
factors affecting corrosion - ANSWER-A. anything that affects polarization. (temp. etc...)
B. concentration cells (oxygen, temp, etc.) In an oxygen concentration cell, what is the anode? (i.e. the area with more or less oxygen?) In a metal ion cell, which area is the anode (i.e. the area with the greater of lower concentration)?
C. Anaerobic bacteria (MIC) Absence of oxygen, depolarizer
polarization - ANSWER-a. corrosion current reduces with polarization
b. polarization increases with CP current applied
c. Occurs at surface of both anode and cathode.
shielding - ANSWER-a. shorted casings
b. proximity of other structures
c. reinforced concrete
amphoteric materials - ANSWER-corrode at low and high pH
on potential - ANSWER-native + polarization + IR drop
polarized potential (off) - ANSWER-native + polarization
kirchoff's laws - ANSWER-a. voltage (series circuits)
b. current (parallel circuits)
faraday's law - ANSWER-W=KIT
relates weight loss of metal in a corrosion cell with time and current flow.
rate of corrosion - ANSWER-directly proportional to current flow
cathodic protection limitations - ANSWER--shielding issues
-attenuation
-interference
-excessive current density
-contact with other metals (shorts)
measurement methods - ANSWER-true voltage reading
voltmeter reading
% error calculations
effect of voltmeter resistance
IR correction methods
test stations - ANSWER-allow electrical connection to structure for potential measurements and bonds.
Spans allow current and direction (IR drop).
inistall during construction
pH - ANSWER-measure of acidity(hydrogen ion concentration)
high pH is alkaline
low pH is acid
pH is a log function therefore each increase in pH is a factor of 10.
RECTIFIER - ANSWER-- positive to anode
-negative to structure
- AC suppy
-AC circuit breaker
-Transformer (increase or decrease voltage)
-AC fuse
-rectifier bridge - diodes change AC to DC
-Voltmeter and Ammeter
-Surge Protection
-Filters
Esecondary = (Eprimary x Secondary turns) / primary turns
Reference electrode location - ANSWER-the reference electrode should be placed as close to the structure as practical. (underground piping or tanks- over the center of the structure, multiple readings along the structure as required)
internal surfaces of storage tanks, waterfront and offshore structures (as close to the wall as possible)
impressed current vs sacrificial - ANSWER-impressed current- higher current, better control
sacrificial- no power required, less maintenance, easy to install, less land
AC considerations - ANSWER-capacitance, inductance, and resistance
hazardous AC potential - 15 Vac
Safe method of connecting ground0 cable to ground then to pipe
arcing hazards
corrosion rates from AC (current density)
switching or pulse rectifiers
Reference cells - ANSWER-CuCuSO4- most common, (soil, fresh water)
AgAgCL - seawater
Calomel- lab
Hydrogen - standard (lab)
zinc- stationary
Cathodic Protection - ANSWER-protect the cathode
attempts to bring the cathode potential as negative as the anode potential
NACE criteria- what are the exceptions?
-high temperature
-bacteria
-sulfides
-acid environments
-dissimilar metals
Isolation Requirement - ANSWER-confine protection to protected structure thus limiting the current required for protection.
use for stray current with care
continuity requirement - ANSWER-bonds are necessary for continuity: mechanical fittings (compression, bell & spigot, rebar etc.)
Impressed Current Anodes - ANSWER-graphite
cast iron (high silicon chromium)
mixed metal oxides
scrap iron
conductive polymer
cylindrical, tubular
soil..... backfilled in coke breeze
current span - ANSWER-current in a pipe can be measured by taking a voltage drop across a known length and either calibrating the section in question or using resistance from tables.
unknown pipe size must be calibrated by using I/ deltamV or R= V/I using 4 wires
Sacrificial anode types - ANSWER-magnesium
zinc
cylindrical, bullet, ribbon, bracelet
soil backfilled in gypsum, bentonite mixture to reduce contact resistance to soil and to retain moisture
make sure to remove plastic shipping bag
small anode to large cathode ratio - ANSWER-higher corrosion penetration rate
large anode to small cathode ratio - ANSWER-lower corrosion penetration rate
4 elements of a corrosion cell - ANSWER-Anode
Cathode
Metallic Patch
Electrolyte
Faraday's law calculates - ANSWER-metal lost due to current over time
the stability of a copper-copper sulfate reference electrode does not vary with - ANSWER-a saturated solution of the copper ions.
if a digital meter displays a negative value while measure a vo
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